Entertainment icon Olivia Newton-John's legendary career immortalized in 17 star-studded duets with her dear friends. Sonic gems spanning five decades of classic hits including "I Honestly Love You" with Jim Brickman and "Put Your Head On My Shoulder" with Paul Anka, as well as brand new fan favorites like "Window in the Wall" featuring Olivia's daughter Chloe Lattanzi. Olivia's duet partners include Mariah Carey, Jon Secada, Barry Gibb, John Travolta, Marie Osmond, Dolly Parton and many more.

- Disc 1 -
1. Suddenly with Cliff Richard
2. Jolene with Dolly Parton
3. Act of Faith with Michael McDonald
4. Window in the Wall with Chloe Lattanzi

- Disc 2 -
1. Take a Chance with John Travolta
2. Put Your Head on My Shoulder with Paul Anka
3. Face to Face with Barry Gibb
4. I Honestly Love You with Jim Brickman

- Disc 3 -
1. The Best of Me with David Foster
2. True to Yourself with Vanessa Amorosi
3. Lost Inside Your Heart with Jon Secada
4. I'll Come Runnin' with Tina Arena

- Disc 4 -
1. Never Far Away with Richard Marx
2. How Can You Mend a Broken Heart with Kelly Lang
3. Stone in My Pocket with Beth Nielsen Chapman & Amy Sky
4. Love Is a Gift with Delta Goodrem
5. Hopelessly Devoted to You with Mariah Carey